Selective Photo-epoxidation of (R)-(+)- and (S)-(−)-Limonene by Chiral and Non-Chiral Dioxo-Mo(VI) Complexes Anchored on TiO2-Nanotubes

Autor:	Fernando Martínez O, Edgar A. Páez-Mozo, Henry Martínez Q.
Rok vydání:	2020
Předmět:	Limonene Schiff base 010405 organic chemistry Ligand General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry Catalysis 0104 chemical sciences chemistry.chemical_compound Bipyridine chemistry Covalent bond Stereoselectivity Terpyridine
Zdroj:	Topics in Catalysis. 64:36-50
ISSN:	1572-9028 1022-5528
Popis:	Selective epoxidation of the (R) and (S) isomers of limonene by dioxomolybdenum(VI) complexes anchored covalently on TiO2 nanotubes using UV–Vis light and O2 as the oxidizing agent was evaluated. It is interesting to study the effect of the ligands: bipyridine, terpyridine, and Schiff base on the stereoselective epoxidation of limonene through photostimulated oxygen atom transfer (OAT). OAT activity observed to increase in the following order: Mo(VI)O2(Schiff base)/TiO2-NT
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7eeffdd78c33226c49899e1538602691 https://doi.org/10.1007/s11244-020-01355-3 Zobrazit plný text záznamu Full text from SpringerLink