A tetraphenylmethane based dendritic tolan–anthracene dyad: synthesis and energy transfer propertiesRespectfully dedicated to Professor Goverdhan Mehta on the occasion of his 60th birthday

Autor:	Pradipta Purkayastha, Saumitra Sengupta
Rok vydání:	2002
Předmět:	Coupling (electronics) Anthracene chemistry.chemical_compound New fuchsin chemistry Energy transfer Dendrimer Organic Chemistry Steady state (chemistry) Physical and Theoretical Chemistry Photochemistry Biochemistry Tetraphenylmethane
Zdroj:	Organic & Biomolecular Chemistry. 1:436-440
ISSN:	1477-0539 1477-0520
DOI:	10.1039/b209186k
Popis:	In order to synthesize a peripherally rigid dendritic donor-acceptor dyad for energy transfer studies, a tritolan dendron based on a tetraphenylmethane scaffold was prepared from New Fuchsin. The dendron showed a small degree of homoconjugation but a large hypochromic effect. Coupling of two such dendrons with an anthracene core led to a dendritic tolan-anthracene dyad whose steady state photophysical studies (UV, PL, PLE) showed vectorial transfer of excitation energy from the surface tolan units to the anthracene core.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7ecaf04e0ed34c3eb2157826fe2f3dba https://doi.org/10.1039/b209186k Zobrazit plný text záznamu