Relative reactivities of isomeric methyl derivatives of phthalic anhydride toward destructive oxidation

Autor:	F. R. Ismagilov, R. M. Masagutov, A. Kh. Sharipov
Rok vydání:	1975
Předmět:	Phthalic anhydride Vanadium chemistry.chemical_element Cleavage (embryo) Ring (chemistry) Medicinal chemistry Catalysis chemistry.chemical_compound chemistry Catalytic oxidation Organic chemistry Pentoxide Reactivity (chemistry) Physical and Theoretical Chemistry
Zdroj:	Reaction Kinetics and Catalysis Letters. 3:391-396
ISSN:	1588-2837 0133-1736
Popis:	The catalytic oxidation of 3,5- and 3,4-dimethylphthalic anhydrides on fused vanadium pentoxide has been studied. Based on the present results and earlier data, the reactivity order of a complete set of mono- and dimethyl derivatives of phthalic anhydride has been established. The results are discussed using quantum-mechanical calculations. The experimental and theoretical data support the assumption that the rate-determining step of destructive oxidation is the cleavage of carbon-carbon bonds in the aromatic ring.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7ea639863dca677637b6f26431ebe5b3 https://doi.org/10.1007/bf02097982 Zobrazit plný text záznamu Full text from SpringerLink