Inductive effects on bridging Ga-Cl distances: The molecular structure of the dichloro(methyl)gallium dimer, [Me2Cl2Ga2(μ-Cl)2], determined by gas electron diffraction

Autor:	Vladimir S. Mastryukov, Hans V. Volden, M.M. Akobiya, L. M. Golubinskaya, Arne Haaland, Snefrid Gundersen, V. I. Bregadze, Igor F. Shishkov
Rok vydání:	1994
Předmět:	Gas electron diffraction Chemistry Stereochemistry Dimer Organic Chemistry chemistry.chemical_element Radial distribution function Biochemistry Inorganic Chemistry Bond length Crystallography chemistry.chemical_compound Molecular geometry Electron diffraction Materials Chemistry Molecule Physical and Theoretical Chemistry Gallium
Zdroj:	Journal of Organometallic Chemistry. 467:161-163
ISSN:	0022-328X
DOI:	10.1016/0022-328x(94)80001-4
Popis:	The gas-phase electron diffraction data for [Me 2 Cl 2 Ga 2 (μ-Cl) 2 ] are consistent with a trans model of C 2 h symmetry and bond distances ( r a ) GaC = 194.9(7) pm, GaCl t = 212.9(3) pm and GaCl b = 233.9(3) pm.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7ea29cad6cca4457491a91bce52abaa4 https://doi.org/10.1016/0022-328x(94)80001-4 Zobrazit plný text záznamu