Spectrophotometric determination of plutonium III, IV, and VI concentrations in nitric acid solution
| Autor: | T. N. Ravi, D. Jebaraj Mahildoss |
|---|---|
| Rok vydání: | 2012 |
| Předmět: |
Molar concentration
Health Toxicology and Mutagenesis Radiochemistry Extraction (chemistry) Public Health Environmental and Occupational Health chemistry.chemical_element Uranium PUREX Pollution Analytical Chemistry Plutonium chemistry.chemical_compound Nuclear Energy and Engineering chemistry Nitric acid Oxidation state Radiology Nuclear Medicine and imaging Absorption (chemistry) Spectroscopy Nuclear chemistry |
| Zdroj: | Journal of Radioanalytical and Nuclear Chemistry. 294:87-91 |
| ISSN: | 1588-2780 0236-5731 |
| DOI: | 10.1007/s10967-012-1614-4 |
| Popis: | The determination of the concentration of various valency states of plutonium is desirable in various stages of the Plutonium/Uranium Recovery by EXtraction (PUREX) process for the effective separation and purification of plutonium. A method is optimized for the quantitative spectrophotometric determination of Pu(III), Pu(IV) and Pu(VI) existing separately or in mixed oxidation states in 1.5 M nitric acid medium. Molar absorption co-efficient (e) for the major absorption peaks with baseline correction are evaluated. With these e data a method is proposed for determining the molar concentration of each oxidation state. |
| Databáze: | OpenAIRE |
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