Nuclear quadrupole structure of potassium hydroxide in the 32 GHz microwave region
| Autor: | T. Yamamura, T. T. Raw, C. W. Gillies |
|---|---|
| Rok vydání: | 1987 |
| Předmět: |
Coupling constant
Potassium hydroxide Spectrometer Analytical chemistry General Physics and Astronomy Resonance symbols.namesake chemistry.chemical_compound Stark effect chemistry Quadrupole symbols Physics::Accelerator Physics Physics::Atomic Physics Physical and Theoretical Chemistry Hyperfine structure Microwave |
| Zdroj: | The Journal of Chemical Physics. 87:3706-3707 |
| ISSN: | 1089-7690 0021-9606 |
| DOI: | 10.1063/1.452973 |
| Popis: | A high temperature Stark and radiofrequency‐microwave double resonance spectrometer was used to observe the nuclear quadrupole structure of the J=2←1 transition of 39KOH in a number of vibrational states. First order analysis of the hyperfine components gave nuclear quadrupole coupling constants of eQq=−7.23 (29) MHz for the (0000) state, eQq=−7.16 (33) MHz for the (1000) state, and eQq=−7.29 (37) MHz for the (0110) state. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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