ChemInform Abstract: Asymmetric Oxidation of Sulfides by Cyclohexanone Monooxygenase
Autor: | Sabrina Dallavalle, Francesco Secundo, Giacomo Carrea, Giuliana Franzosi |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 25 |
ISSN: | 0931-7597 |
DOI: | 10.1002/chin.199402057 |
Popis: | Cyclohexanone monooxygenase catalyzes the asymmetric oxidazion of numerous alkyl aryl sulfides with the alkyl chain functionalyzed with Cl, CN, vinyl or hydroxy groups. Sulfoxides with enantiomeric excesses up to 99% were obtained. The structure of the sulfide markedly influenced enzyme enantioselectivity. |
Databáze: | OpenAIRE |
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