ChemInform Abstract: Asymmetric Oxidation of Sulfides by Cyclohexanone Monooxygenase

Autor: Sabrina Dallavalle, Francesco Secundo, Giacomo Carrea, Giuliana Franzosi
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 25
ISSN: 0931-7597
DOI: 10.1002/chin.199402057
Popis: Cyclohexanone monooxygenase catalyzes the asymmetric oxidazion of numerous alkyl aryl sulfides with the alkyl chain functionalyzed with Cl, CN, vinyl or hydroxy groups. Sulfoxides with enantiomeric excesses up to 99% were obtained. The structure of the sulfide markedly influenced enzyme enantioselectivity.
Databáze: OpenAIRE