Optical spectroscopy of Nd3+ions in poly(acrylic acid)

Autor:	F Ramos-Lara, A Lira C, M O Ramírez, M Flores, R Arroyo, U Caldiño
Rok vydání:	2006
Předmět:	Quantitative Biology::Biomolecules Analytical chemistry Condensed Matter Physics chemistry.chemical_compound Monomer chemistry Polymerization Excited state General Materials Science Spontaneous emission Stimulated emission Spectroscopy Ground state Acrylic acid
Zdroj:	Journal of Physics: Condensed Matter. 18:7951-7959
ISSN:	1361-648X 0953-8984
DOI:	10.1088/0953-8984/18/34/008
Popis:	Nd3+ dissolved in solid poly(acrylic acid) was synthesized by polymerization of the monomer partially neutralized with neodymium hydroxide in aqueous solution. The monomer modification and the coordination of ligands to Nd3+ were confirmed by 1H NMR spectroscopy. The measured oscillator strengths for transitions from the ground state to the main excited state manifolds compared favourably with calculated electric dipole oscillator strengths. The spontaneous emission rates, the fluorescence branching ratios and the stimulated emission cross sections of the , and transitions, as well as the radiative lifetime and the quantum efficiency of the 4F3/2 emitting level, were determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7e70e82c4ba6c6fd660734cc18e43867 https://doi.org/10.1088/0953-8984/18/34/008 Zobrazit plný text záznamu