Intramolecular diels-alder reactions of dienamines with acrylates: trends in stereoselectivity upon substitution

Autor:	K. N. Houk, Tse-Chong Wu
Rok vydání:	1985
Předmět:	Bicyclic molecule Intramolecular reaction Organic Chemistry Substitution (logic) Biochemistry Cycloaddition Enamine chemistry.chemical_compound chemistry Intramolecular force Drug Discovery Organic chemistry Stereoselectivity Diels–Alder reaction
Zdroj:	Tetrahedron Letters. 26:2293-2296
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)95078-0
Popis:	Intramolecular Diels-Alder reactions of all- trans ethyl 10-diethylamino-2,7,9-decatrienoate and 11-diethylamino-2,8,10-trienoate occur readily to produce trans and cis -fused products in ratios of 85:15 and 55:45, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7e5f5db675673a59380cef39dd896227 https://doi.org/10.1016/s0040-4039(00)95078-0 Zobrazit plný text záznamu