ChemInform Abstract: Difluoromethyldiphenylphosphine Oxide. A New Reagent for Conversion of Carbonyl Compounds to 1,1-Difluoroolefins

Autor:	James R. McCarthy, Esa T. Jarvi, Donald P. Matthews, Stemerick David M, Edwards Michael L
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Chemistry Reagent Chlorodifluoromethane Oxide Organic chemistry General Medicine Diphenylphosphine oxide
Zdroj:	ChemInform. 22
ISSN:	0931-7597
DOI:	10.1002/chin.199140184
Popis:	Difluoromethyldiphenylphosphine oxide ( 5 ) was synthesized from chlorodifluoromethane and diphenylphosphine oxide. Reaction of 5 with a variety of ketones and aldehydes gave 1,1-difluoroolefins. Monofluoromethyldiphenylphosphine oxide ( 7 ) was also synthesized but did not give monofluoroolefins.
Databáze:	OpenAIRE
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