Reactions of hydroxyl and nitrogen trioxide radicals with phenol, cresols, and 2-nitrophenol at 296 .+-. 2 K

Autor:	Roger Atkinson, Janet Arey, Sara M. Aschmann
Rok vydání:	1992
Předmět:	Chemistry Radical General Chemistry Cresol Photochemistry Nitrophenol chemistry.chemical_compound Reaction rate constant Nitrogen trioxide 2-nitrophenol medicine Environmental Chemistry Molecule Phenol medicine.drug
Zdroj:	Environmental Science & Technology. 26:1397-1403
ISSN:	1520-5851 0013-936X
DOI:	10.1021/es00031a018
Popis:	The nitrophenol products from the gas-phase reactions of OH and NO 3 radicals with phenol and the cresols in the presence of NO x have been investigated and rate constants for the reactions of the NO 3 radical with phenol, the cresols, and 2-nitrophenol determined at 296±2 K. The rate constants obtained were (in cm 3 molecule -1 s -1 ) phenol, 3.92×10 -12 ; o-cresol, 1.37×10 -11 ; m-cresol, 9.74×10 -12 ; p-cresol, 1.07×10 -11 ; and 2-nitrophenol
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7e369d4c5f1147214a5f8e7312fbecb1 https://doi.org/10.1021/es00031a018 Zobrazit plný text záznamu