Studies on the reactions of transition metal hydrides with heterocumulenes
| Autor: | Mei Wang, Zhongsheng Jin, He-Fu Guo, Meizhi Bei, Shi-Wei Lu |
|---|---|
| Rok vydání: | 1993 |
| Předmět: |
chemistry.chemical_classification
Schiff base Stereochemistry Organic Chemistry chemistry.chemical_element Crystal structure Biochemistry Medicinal chemistry Ruthenium Inorganic Chemistry chemistry.chemical_compound chemistry Transition metal Materials Chemistry Osmium Iridium Physical and Theoretical Chemistry Metallocene Thioamide |
| Zdroj: | Journal of Organometallic Chemistry. 447:227-231 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/0022-328x(93)80243-5 |
| Popis: | The novel N,S-containing zirconacycle complexes CP 2 ZrCl[SC(H)NR] ( 1a , R C 6 H 5 ; 1b , R 2-C 10 H 7 ; 1c , R c-C 6 H 11 ; 1d , R n-C 4 H 9 ) were obtained by insertion reactions of CP 2 Zr(H)Cl with RNCS. 1 ( a–d ) could react further with CP 2 Zr(H)Cl to yield a sulphur-bridging complex (Cp 2 ZrCl) 2 S ( 2 ) and a Schiff base RNCH 2 . The crystal structure of 1a has been determined by X-ray analysis. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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