Octafluorocyclooctatetraene transition metal compounds: displacement of fluoride by metal carbonyl anions
| Autor: | Deborah E. Samkoff, Wayne L. Smith, Stephen J. Doig, Russell P. Hughes, Steven L. Patt |
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| Rok vydání: | 1983 |
| Předmět: |
Organic Chemistry
Inorganic chemistry Metal carbonyl Ring (chemistry) Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound Cyclooctatetraene chemistry Transition metal Yield (chemistry) Materials Chemistry Physical and Theoretical Chemistry Fluoride Derivative (chemistry) |
| Zdroj: | Journal of Organometallic Chemistry. 250:c1-c4 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/0022-328x(83)85083-9 |
| Popis: | Octafluorocyclooctatetraene (OFCOT) reacts with some metal carbonyl anions [MLn]− to give monosubstitution products (C8F7)MLn [MLn = Mn(CO)5, Re(CO)5, Fe(CO)2(η-C5H5)]. 19F and 13C {19F} NMR studies show that the cyclooctatetraene ring in these monosubstitution products does not undergo rapid ring-inversion or bond shifting on the NMR time scale. Reaction of OFCOT with [Co(CO)4]− affords the distributed derivative [(C8F6)Co2(CO)6] as the only product in poor yield. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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