The role played by some factors of intramolecular interaction in nonradiative deactivation of the lowest triplet state of octachlorodibenzo-p-dioxin

Autor:	L. V. Volkova, E. A. Gastilovich, R. N. Nurmukhametov, V. G. Klimenko
Rok vydání:	2012
Předmět:	Physics Reaction rate constant Intramolecular force Molecular vibration Molecule Physics::Atomic Physics Physics::Chemical Physics Triplet state Atomic physics Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials Octachlorodibenzo-p-dioxin
Zdroj:	Optics and Spectroscopy. 113:463-473
ISSN:	1562-6911 0030-400X
DOI:	10.1134/s0030400x12090044
Popis:	We have studied how intramolecular interactions, such as vibronically induced spin-orbit (VISO) and nonadiabatic interactions, which are governed by different structural elements of the octachlorodibenzo-p-dioxin (OCDD) molecule, affect the deactivation of its lowest triplet state. In the nonadiabatic approximation, taking into account out-of-plane vibrational modes as promoting ones, we have estimated the values of rate constant Kdgs of the nonradiative energy deactivation of in-plane triplet sublevels (s = z, y) of the triplet state of the OCDD molecule.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7df413a0df259cca575257fa542acb0a https://doi.org/10.1134/s0030400x12090044 Zobrazit plný text záznamu Plný text ve formátu PDF