Interconversion between Platinum(II) and Platinum(0) with Change of pH: Aqueous Reactions of Pt(H)(TPPTS)3+ (TPPTS = P(m-C6H4SO3Na)3)

Autor:	Jim D. Atwood, Derrik S. Helfer and
Rok vydání:	2001
Předmět:	Inorganic Chemistry chemistry.chemical_compound Aqueous solution chemistry Oxidation state Organic Chemistry Inorganic chemistry chemistry.chemical_element Physical and Theoretical Chemistry TPPTS Platinum
Zdroj:	Organometallics. 21:250-252
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om010896w
Popis:	The oxidation state for platinum complexes of TPPTS can be controlled through variation of the pH of an aqueous solution. Thus Pt(H)(TPPTS)3+ dissolved in H2O gives a well-characterized Pt(II)−H complex at neutral or acidic pH but exists as Pt(TPPTS)3 at pH ≥12.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7df3ce99d9400df3641ab4edbdfbb094 https://doi.org/10.1021/om010896w Zobrazit plný text záznamu