Synthesis, structure and reactivity study of 1,1′-bis(N-ter-butyl-N-hydroxyamino)ferrocene
| Autor: | B.J.L. Henner, Carsten Uerpmann, Christian Guérin, Francis Carré |
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| Rok vydání: | 2002 |
| Předmět: |
Chemistry
Organic Chemistry chemistry.chemical_element Biochemistry Medicinal chemistry Nitrogen Inorganic Chemistry chemistry.chemical_compound Hydroxylamine Ferrocene Group (periodic table) Materials Chemistry Organic chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Chemical decomposition |
| Zdroj: | Journal of Organometallic Chemistry. 654:210-215 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(02)01365-7 |
| Popis: | The synthesis of 1,1′-bis(N-ter-butyl-N-hydroxyamino)ferrocene 1, is described, and the X-ray analysis showed eclipsed positions of the two ter-butylhydroxyamino groups; this structure can be explained by the interactions of the hydroxyl hydrogens with the nitrogen atoms of the other ter-butylhydroxyamino group. This interaction is maintained in solution and may explain that the oxidation of 1 using Ag2O gave a decomposition reaction instead of the expected 1,1′-bis(N-ter-butylaminoxy)ferrocene. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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