Synthesis and crystal structure of anhydrous copper suberate: [Cu2(OOC-(CH2)6 -COO)2]

Autor:	Thierry Roisnel, Achoura Guehria-Laïdoudi, Fadila Balegroune, Assia Djeghri
Rok vydání:	2006
Předmět:	chemistry.chemical_element General Chemistry Crystal structure Triclinic crystal system Condensed Matter Physics Copper chemistry.chemical_compound Crystallography chemistry Square pyramid Intramolecular force Anhydrous Single crystal Organometallic chemistry
Zdroj:	Journal of Chemical Crystallography. 37:97-101
ISSN:	1572-8854 1074-1542
DOI:	10.1007/s10870-006-9154-9
Popis:	The title compound [Cu2(OOC-(CH2)6-COO)2] was synthesized and its crystal structure has been determined by single crystal X-ray diffraction methods. The complex crystallizes in the triclinic space group P-1 with a=5.1077(5) A, b=8.362(2) A, c=11.378(2) A, α=93.773(6)°, β=97.587(9)°, γ=90.493(’9)° and D cal=1.629 mg/m3 for Z=1. The structure is polymeric and consists of discrete anhydrous centrosymmetric binuclear units [Cu2(OOC-(CH2)6-COO)2]. The two copper(II) centres bridged by the suberate groups in a syn-syn conformation, are in pentacoordinated distorted square-pyramidal coordination environment, with an intramolecular Cu–Cu distance of 2.5793(10) A. Each binuclear unit, related to the next through μoxo bridges with a Cuμoxo–Cuμoxo separation of 3.2326(10)A, defines infinite chains of one-edge sharing CuO5 square pyramid.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7decca262e7527f3ae9e1711ba948bb3 https://doi.org/10.1007/s10870-006-9154-9 Zobrazit plný text záznamu Full text from SpringerLink