Autor: |
Elies Molins, Gregorio López, Carles Miravitlles, José Antonio Giner, Venancio Rodríguez, Jaume Casabó, José Ruiz |
Rok vydání: |
2000 |
Předmět: |
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Zdroj: |
Polyhedron. 19:1627-1631 |
ISSN: |
0277-5387 |
DOI: |
10.1016/s0277-5387(00)00440-x |
Popis: |
Heterodinuclear complexes of the types [(dppe)M(μ-SR)2Pd(η3-allyl)][ClO4] (M=Pd or Pt) and [(dppe)Pt(μ-SC2H4S)Pd(η3-allyl)][ClO4] [dppe=1,2-bis(diphenylphosphino)ethane; allyl=C3H5 or C4H7] have been obtained by reaction of the corresponding cis-dithiolato complexes, [M(SR)2 (dppe)] or [Pt(SC2H4S)(dppe)], and [Pd(η3-allyl)(PhCN)2][ClO4]. The identity of these complexes has been established by NMR (1H and 31P) spectroscopy. The crystal structure of [(dppe)Pd(μ-SC6H4Me-p)2Pd(η3-C3H5)][ClO4] has been determined by single-crystal X-ray methods. The p-tolyl groups on the sulfur atoms adopt a syn conformation with respect to the central PdS2Pd core. |
Databáze: |
OpenAIRE |
Externí odkaz: |
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