Crystal structures and physical properties of DIMET triiodides
| Autor: | Koichi Kikuchi, Harukazu Yoshino, M. Ishibashi, Isao Ikemoto, Tadashi Mochiduki, Haruhiko Itoh, Hideki Saitoh, Kazuya Saito |
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| Rok vydání: | 1992 |
| Předmět: |
Stereochemistry
Mechanical Engineering Dimer Metals and Alloys Crystal structure Condensed Matter Physics Electronic Optical and Magnetic Materials Pressure range Crystal chemistry.chemical_compound Crystallography chemistry Mechanics of Materials Electrical resistivity and conductivity Seebeck coefficient Materials Chemistry Molecule Isostructural |
| Zdroj: | Synthetic Metals. 52:87-100 |
| ISSN: | 0379-6779 |
| DOI: | 10.1016/0379-6779(92)90022-b |
| Popis: | Crystals of DIMET·I 3 and (DIMET) 2 I 3 are prepared and their crystal structures determined. The crystal of DIMET·I 3 consists of DIMET dimer and I 3 anions. (DIMET) 2 I 3 is isostructural with (DMET) 2 I 3 , in which the donor molecules form columns. DIMET·I 3 is an insulator. The resistivity under pressure and thermoelectric power are measured for (DIMET) 2 I 3 . A metal-insulator transition is detected at about 41 K under normal pressure. Physical properties are compared with those of (DMET) 2 I 3 . |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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