Autor:	Jean-Pierre Fouassier, Roland Reeb, Gilles Eisele
Rok vydání:	1996
Předmět:	Acrylate polymer Acrylate Reaction mechanism Polymers and Plastics Organic Chemistry Kinetics Condensed Matter Physics chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Benzophenone Physical and Theoretical Chemistry Fourier transform infrared spectroscopy
Zdroj:	Macromolecular Chemistry and Physics. 197:1731-1756
ISSN:	1521-3935 1022-1352
DOI:	10.1002/macp.1996.021970514
Popis:	The study of the mechanism of the processes taking place in photocrosslinking of the homopolymer of dicyclopentenyl acrylate (DCPA), was realized using ultraviolet and Fourier transform infrared (FTIR) measurements. Different kinetics of crosslinking in the presence and absence of benzophenone prove the efficiency of this photosensitive system. The particular structure of the acrylic matrix of poly(DCPA), i.e., the presence of a residual unsaturated bond and a cyclic structure, reveals its high photooxidation potential (hydroperoxyde formation as detected by FTIR between 3 300 and 3600 cm -1 ).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7db56d66f9ccc8aad903f7bc5019d50e https://doi.org/10.1002/macp.1996.021970514 Zobrazit plný text záznamu Plný text