Evaluation of dye-micelle binding constants using diffusion sensitive band broadening effects
| Autor: | Soon M. Han, Daniel W. Armstrong, Randy A. Menges |
|---|---|
| Rok vydání: | 1988 |
| Předmět: |
Aqueous solution
Chemistry Diffusion Inorganic chemistry Micelle Surfaces Coatings and Films Electronic Optical and Magnetic Materials Biomaterials chemistry.chemical_compound Colloid Colloid and Surface Chemistry Solubilization Organic dye Physical chemistry Sodium dodecyl sulfate Dispersion (chemistry) |
| Zdroj: | Journal of Colloid and Interface Science. 126:239-242 |
| ISSN: | 0021-9797 |
| Popis: | The diffusion coefficients of small solutes can be significantly altered by the presence of association colloids such as micelles. A relationship is utilized that relates the diffusion coefficient of a solute to its partitioning or binding behavior to a micellar pseudophase. The Taylor-Aris dispersion method was used to evaluate the diffusion coefficient of several dyes in the presence and absence of sodium dodecyl sulfate micelles. With this approach, all binding constants can be determined easily and reproducibly. The theory, experimental approach, and advantages of this technique are discussed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|