Stereoselective reactions. VII. Synthesis of racemic and optically pure stegane, isostegane, picrostegane, and isopicrostegane via highly selective isomerization

Autor:	Kiyoshi Tomioka, Kenji Koga, Tsuneo Ishiguro, Hidemichi Mizuguchi
Rok vydání:	1985
Předmět:	chemistry.chemical_classification Chemistry Stereochemistry Enantioselective synthesis General Chemistry General Medicine Nuclear magnetic resonance spectroscopy Carbon-13 NMR chemistry.chemical_compound Drug Discovery Steganacin Stereoselectivity Enantiomer Isomerization Lactone
Zdroj:	Chemical and Pharmaceutical Bulletin. 33:121-126
ISSN:	1347-5223 0009-2363
DOI:	10.1248/cpb.33.121
Popis:	Novel isomerizations of isostegane (6) into the three other possible isomers, namely, isopicrostegane (7), picrostegane (8), and stegane (9) are described. All the possible enantiomers were synthesized.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7d66e0d40dd51af906752ee9a592ca5b https://doi.org/10.1248/cpb.33.121 Zobrazit plný text záznamu