Molmassen-bestimmungen und leitfähigkeits-messungen an olefin- und basen-goldchlorid-komplexen. Ein beitrag zur konstitution
| Autor: | H. Coutelle, Rudolf Hüttel |
|---|---|
| Rok vydání: | 1978 |
| Předmět: |
chemistry.chemical_classification
Olefin fiber Base (chemistry) Coordination number Norbornadiene Organic Chemistry Electrolyte Biochemistry Ion Coordination complex Inorganic Chemistry chemistry.chemical_compound chemistry Electrical resistivity and conductivity Polymer chemistry Materials Chemistry Organic chemistry Physical and Theoretical Chemistry |
| Zdroj: | Journal of Organometallic Chemistry. 153:359-368 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)92059-x |
| Popis: | According to measurements of molecular weight and electric conductivity of complexes of gold chlorides with olefins and bases in solution, the coordination compounds olefin · AuCl, base · AuCl and base · AuCl3 are dissolved monomerically and non-dissociatedly, but the “mixed complexes” olefin2 · Au2Cl4, olefin3 · Au2Cl4 and base2 - Au2Cl4 are present essentially as 1 1 -electrolytes in polarizing solvents (with AuCl4− as anion). The compound norbornadiene · Au2Cl4, however, seems not to be dissociated, or only to a small extent since only thus can Au(I) attain its coordination number 2. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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