Energy Efficient Synthesis of Ordered Mesoporous Carbon Nitrides with a High Nitrogen Content and Enhanced CO 2 Capture Capacity
| Autor: | Kripal S. Lakhi, Ajayan Vinu, Siddulu Naidu Talapaneni, Kavitha Ramadass, Ugo Ravon, Stalin Joseph, Dae-Hwan Park, Minkyu Kim, Khalid Al-Bahily |
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| Rok vydání: | 2017 |
| Předmět: |
Organic Chemistry
Inorganic chemistry chemistry.chemical_element 02 engineering and technology General Chemistry Nitride Mesoporous silica 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Nitrogen Catalysis 0104 chemical sciences Nanomaterials Mesoporous organosilica chemistry Gas separation 0210 nano-technology Carbon Stoichiometry |
| Zdroj: | Chemistry – A European Journal. 23:10753-10757 |
| ISSN: | 1521-3765 0947-6539 |
| Popis: | Highly ordered mesoporous carbon nitrides (MCN) with 3D structure and a high nitrogen content are successfully prepared for the first time using "uncalcined" mesoporous silica template, KIT-6 and 3-amino-1,2,4-triazole as a single molecular carbon and nitrogen precursor. The prepared MCN with C and N stoichiometry of C3 N5 shows unique CN framework and exhibits the CO2 capture capacity of 5.63 mmol g-1 at 273 K and 30 bar, which is higher than that of MCN with 2D structure and C3 N4 stoichiometry. |
| Databáze: | OpenAIRE |
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