Effect of support modification and precursor decomposition method on the properties of CoPt/ZrO2 Fischer–Tropsch catalysts
| Autor: | Sufang Chen, Guiqin Xiao, Jingping Hong, Jinlin Li, Fuzhen Zhao, Yaoyao Han, Muhua Chen, Yuhua Zhang |
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| Rok vydání: | 2021 |
| Předmět: |
inorganic chemicals
Nanostructure Materials science chemistry.chemical_element Fischer–Tropsch process Plasma treatment 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Decomposition Catalysis 0104 chemical sciences chemistry X-ray photoelectron spectroscopy Chemical engineering 0210 nano-technology Cobalt |
| Zdroj: | Catalysis Today. 375:1-9 |
| ISSN: | 0920-5861 |
| Popis: | A series of CoPt/ZrO2 catalysts using plasma treatment to modify ZrO2 support and/or to decompose the cobalt precusor were prepared. The nanostructure and properties of the supports and catalysts were characterized by N2-physisorption, SEM, TEM, XRD, XPS, H2-TPR and H2-TPD, and the catalytic performance of four catalysts was evaluated by Fischer-Tropsch synthesis (FTS) reaction. Characterization results showed that defects were created and morphology change was achieved on ZrO2 support by plasma modification. The synegetic effect of plasma support modification and precursor decomposition resulted in extremely high dispersion of cobalt species (∼ 1 nm), these highly dispersed cobalt particles also had improved reduction ablibity, and thus a plentiful number of active sites were generated, despite its lower TOF value, a highest apparent FT activity was presented. |
| Databáze: | OpenAIRE |
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