Crystal structure of p-nitroanilinium hexafluorosilicate

Autor:	V. S. Sergienko, V. O. Gel’mbol’dt, L. Kh. Minacheva, Edward V. Ganin
Rok vydání:	2006
Předmět:	Inorganic Chemistry Diffraction chemistry.chemical_compound Crystallography Chemistry Materials Science (miscellaneous) Ionic bonding Crystal structure Methanol Physical and Theoretical Chemistry
Zdroj:	Russian Journal of Inorganic Chemistry. 51:1561-1564
ISSN:	1531-8613 0036-0236
Popis:	Complex (p-O2NC6H4NH3)2SiF6 (I) is prepared by reacting fluorostlicic acid with p-nitroaniline in methanol and structurally studied using single-crystal X-ray diffraction. In the ionic structure of this complex, SiF 6 2− centrosymmetrical anions (avg. Si-F, 1.671(3) A) and O2NC6H4NH 3 + cations are linked through NH…F interionic H-bonds (N…F 2.823(5)-3.205(7) A). The thermochemical features of complex I are discussed in light of the structure data.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7cdb6b3a94d47e5fb1cadf484c6579b8 https://doi.org/10.1134/s0036023606100081 Zobrazit plný text záznamu Full text from SpringerLink