Rotational conformation of 8,8′-dihalogenated derivatives of cobalt bis(dicarbollide) in solution

Autor:	Igor B. Sivaev, Irina D. Kosenko
Rok vydání:	2021
Předmět:	chemistry 010405 organic chemistry Hydrogen bond Intramolecular force Proton NMR chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Cobalt Medicinal chemistry 0104 chemical sciences
Zdroj:	Russian Chemical Bulletin. 70:753-756
ISSN:	1573-9171 1066-5285
Popis:	The 1H NMR study demonstrated that the transoid conformation of dihalogenated derivatives of cobalt bis(dicarbollide) [8,8′-X2-3,3′-Co(1,2-C2B9H10)2]− (X = Cl, Br, I), stabilized by intramolecular $$\text{C} - \text{H} \cdots \text{X}$$ hydrogen bonds between ligands, is retained in solution.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7cd9eb0d8b943747289a0bb4366c6302 https://doi.org/10.1007/s11172-021-3146-y Zobrazit plný text záznamu Full text from SpringerLink