Efficient Synthesis of Vinyl Sulfones by Manganese-Catalyzed Decarboxylative Coupling of Cinnamic Acids with Aromatic Sulfinic Acid Sodium Salts
| Autor: | Wei Deng, Xinman Tu, Weiping Luo, Jiannan Xiang, Na Xue, Ruqing Guo |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Tetrahydrate 010405 organic chemistry Decarboxylation Dimethyl sulfoxide organic chemicals Organic Chemistry Iodide chemistry.chemical_element Manganese Sulfinic acid 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis Solvent chemistry.chemical_compound chemistry Organic chemistry |
| Zdroj: | Synlett. 27:2695-2698 |
| ISSN: | 1437-2096 0936-5214 |
| DOI: | 10.1055/s-0035-1562476 |
| Popis: | An efficient synthesis of vinyl sulfones is described. Reactions of cinnamic acids with aromatic sulfinic acid sodium salts in the presence of a catalytic amount of manganese(II) acetate tetrahydrate (5 mol%) in dimethyl sulfoxide (DMSO) afforded the desired vinyl sulfones in good to excellent yields. Notably, the reaction does not need any base or iodide as additive. The use of DMSO as the solvent and running the reaction under air are critical in achieving good yields. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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