Interaction Between Fumed-Silica and Epoxidized Natural Rubber
| Autor: | Zheng Peng, Yong Yue Luo, Jie Ping Zhong, Yongzhen Li, Can Zhong He, Yue Qiong Wang |
|---|---|
| Rok vydání: | 2011 |
| Předmět: |
Thermogravimetric analysis
Materials science Polymers and Plastics Scanning electron microscope Dynamic mechanical analysis Natural rubber visual_art Ultimate tensile strength Materials Chemistry visual_art.visual_art_medium Fourier transform infrared spectroscopy Composite material Glass transition Fumed silica |
| Zdroj: | Journal of Inorganic and Organometallic Polymers and Materials. 21:777-783 |
| ISSN: | 1574-1451 1574-1443 |
| DOI: | 10.1007/s10904-011-9539-x |
| Popis: | Epoxidized natural rubber (ENR)/fumed silica vulcanizates were prepared by mechanical mixing method. Fumed silica content can affect mechanical properties of the composites, and ten parts per hundreds of rubber (phr) fumed silica lead to the best tensile strength. The interaction between ENR and fumed silica was characterized by Kraus equation, crosslink density (tested by NMR), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and scanning electron microscope (SEM). The results showed that the dispersion of silica in ENR was better than in natural rubber (NR), hydrogen bond was produced between ENR and fumed-silica in ENR/silica blends, and glass transition temperature of ENR/silica vulcanizate was higher than pure ENR vulcanizate. TGA and DMA confirmed that there was intense interaction between ENR and silica. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink