ChemInform Abstract: Imprinted Polymers: Versatile New Tools in Synthesis

Autor:	Michael J. Whitcombe, Cameron Alexander, E. N. Vulfson
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Acylation chemistry.chemical_compound chemistry Molecularly imprinted polymer Benzisoxazole Organic chemistry Aldol condensation General Medicine Transesterification Polymer Condensation reaction Isomerization
Zdroj:	ChemInform. 31
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200036278
Popis:	The use of molecularly imprinted polymers in synthetic organic chemistry is reviewed. These materials are prepared in the presence of a template for which they carry a functional and stereo- chemical "memory" and can be likened to artificial antibodies or enzymes. Their unique properties have been exploited by the use of imprinted polymers as stereo- and regio-selective solid supports in condensation reactions and hydride reduction, as protecting groups in the acylation of polyols and as catalysts to enhance the rates of reactions as diverse a Diels-Alder reaction, an Aldol condensation, β-elimination, the benzisoxazole isomerization, transesterification and ester hydrolyses.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7c21dac3570f2ac21b8aaf6bc241e9b0 https://doi.org/10.1002/chin.200036278 Zobrazit plný text záznamu Plný text