Transition metal complexes of a hydrazone derived from hydralazine hydrochloride and 3,5-di-tert-butylsalicylaldehyde
| Autor: | Umashri Kendur, Sunil Jalalpure, Sunil M. Patil, Geeta H. Chimmalagi, Ramesh S. Vadavi, Kalagouda B. Gudasi, Suneel Dodamani, Christopher S. Frampton |
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| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Monobasic acid Inorganic chemistry Hydrazine Metals and Alloys Hydrazone Crystal structure 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Coordination complex Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Transition metal Materials Chemistry Organometallic chemistry |
| Zdroj: | Transition Metal Chemistry. 43:65-72 |
| ISSN: | 1572-901X 0340-4285 |
| Popis: | Mononuclear Co(III), Ni(II) and Cu(II) coordination compounds of (E)-1-(3,5-di-tert-butyl-2-hydroxybenzylidene)-2-(phthalazin-1-yl)hydrazine (LH) were prepared and characterized by physicochemical and spectroscopic methods. The metal-to-ligand ratio was found to be 1:2 in [Co(L)2]Cl·2H2O (1) and [Ni(L)2]·2H2O (2), while it is 1:1 in [Cu(L)Cl]·2CH3OH (3). The X-ray crystal structures of LH and complex 1 is are reported. LH shows monobasic behavior, coordinating through NNO donor atoms. The complexes were investigated for their antimicrobial properties. Complexes 1 and 3 show excellent antibacterial and antifungal activities, respectively. |
| Databáze: | OpenAIRE |
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