Hydrogen bond and proton transfer in complexes of trioctylamine with halogenoacetic acids

Autor:	A. L. Smolyansky, G. V. Gusakova, Gleb S. Denisov
Rok vydání:	1973
Předmět:	Inorganic Chemistry Proton Hydrogen bond Chemistry Organic Chemistry Low-barrier hydrogen bond Infrared spectroscopy Ionic bonding Amine gas treating Photochemistry Spectroscopy Analytical Chemistry
Zdroj:	Journal of Molecular Structure. 15:377-382
ISSN:	0022-2860
DOI:	10.1016/0022-2860(73)80006-7
Popis:	The infrared spectra of solutions containing trioctylamine and monohalogenoacetic acids have been investigated in the region 1500–1800 cm −1 . Two forms of complexes 1: 1 acid-amine, the molecular complex with hydrogen bond OH N and the ionic pair, resulting from proton transfer from acid to amine, have been found to exist in equilibrium with each other.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7c0f8055ea4b623255c36e5f3919373f https://doi.org/10.1016/0022-2860(73)80006-7 Zobrazit plný text záznamu