Synthesis ofo-andm-carborane derivatives of [2,2]paracyclophane and abnormal Clemmensen reduction of ketones of the [2,2]paracyclophane and carborane series

Autor:	L. E. Vinogradova, L. I. Zakharkin, Valentina A. Ol'shevskaya
Rok vydání:	1997
Předmět:	chemistry.chemical_compound Ethanol chemistry Stereochemistry Carborane chemistry.chemical_element General Chemistry Clemmensen reduction Zinc Medicinal chemistry
Zdroj:	Russian Chemical Bulletin. 46:1158-1163
ISSN:	1573-9171 1066-5285
Popis:	Methods for the synthesis of [2,2]paracyclophane derivatives containingo- andm-carboranyl substituents in position 4, separated from the [2,2]paracyclophane system by one or two C atoms (alcohols and ketones) were developed. The Clemmensen reduction of a number of ketones of the [2,2]paracyclophane ando-carbonane series occurs abnormally. The reduction of 1-benzoyl-o-carboranes to the corresponding alcohols by zinc in ethanol in a neutral medium was performed for the first time.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7bf3d0f90853e60fef4ba7c7b16a002c https://doi.org/10.1007/bf02496219 Zobrazit plný text záznamu Full text from SpringerLink