Thermospray LC/MS applied to the analysis of complex mixtures of non-polar materials
| Autor: | J. R. Joyce, I. A. S. Lewis, R. E. Ardrey |
|---|---|
| Rok vydání: | 1985 |
| Předmět: |
Chromatography
Chemistry Chemical polarity Analytical chemistry Ionic bonding Thermospray Mass spectrometry Biochemistry Liquid chromatography–mass spectrometry Ionization Molecular Medicine Direct electron ionization liquid chromatography–mass spectrometry interface Spectroscopy Electron ionization |
| Zdroj: | Biological Mass Spectrometry. 12:588-592 |
| ISSN: | 1096-9888 1052-9306 |
| DOI: | 10.1002/bms.1200121004 |
| Popis: | A thermospray liquid chromatograph/mass spectrometer interface has been applied to the analysis of non-polar materials. The interface, which is designed to permit the continuous introduction of liquid into a mass spectrometer, incorporates a new ionization technique, which has proved capable of ionizing polar compounds and species which are ionic in solution. This new ionization method has been successfully applied to the analysis of a complex mixture of phenanthrenic materials. The results have been compared with data obtained by electron impact LC/MS and demonstrate the utility of thermospray ionization in the liquid chromatographic/mass spectrometric screening for compounds in this class, and suggest that the technique may be applied to a wide variety of non-polar compounds. |
| Databáze: | OpenAIRE |
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