Introducing a flexible and Y-shaped tricarboxylic acid linker into functional complex: Photocatalytic dye degradation

Autor:	Jun-Cheng Jin, Jun Wang, Xun Cai, Cheng-Gen Xie, Ying-Lao Zhang, Mohd. Muddassir, Zhen Liu, Wanping Wang, Hiroshi Sakiyama
Rok vydání:	2022
Předmět:	chemistry.chemical_classification Organic Chemistry Supramolecular chemistry Tricarboxylic acid Metallacycle Analytical Chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Photocatalysis Rhodamine B Methylene Linker Spectroscopy Methylene blue
Zdroj:	Journal of Molecular Structure. 1250:131867
ISSN:	0022-2860
Popis:	A new complex, namely, [Cu2(HL)2(H2O)2(phen)2]·H2O (H3L=1,3,5-tris(4-carbonylphenyloxy)benzene, phen = 1,10-phenanthroline) (1) was solvothermally prepared and characterized. 1 exhibited a three-dimensional supramolecular network built by 0D metallacycle through hydrogen-bonding and π–π interactions. The photocatalytic degradation feature of 1 was studied. The results declared 1 has photocatalytic activities with 46.87%, 10.17% and 22.86% for methylene blue, methylene orange and Rhodamine B after 100 min, respectively. The plausible mechanism of catalytic degradation toward MB in the presence of 1 was proposed using the trapping method and LC-MS studies.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7bd537fa11a100e8222b56aa15be441e https://doi.org/10.1016/j.molstruc.2021.131867 Zobrazit plný text záznamu Full Text from ScienceDirect