Fluoroorganic sulphur-containing compounds. II. The synthesis of perfluoro-2,3-dihydrobenzo[b]thiophene and an investigation of some of its chemical properties
Autor: | Alexander M. Maksimov, V. E. Platonov, P. I. Maslovsky |
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Rok vydání: | 1995 |
Předmět: |
Organic Chemistry
Infrared spectroscopy Nuclear magnetic resonance spectroscopy Biochemistry Inorganic Chemistry chemistry.chemical_compound Ultraviolet visible spectroscopy chemistry Nucleophile Oxidizing agent Thiophene Environmental Chemistry Organic chemistry Tetrafluoroethylene Physical and Theoretical Chemistry Pyrolysis |
Zdroj: | Journal of Fluorine Chemistry. 75:41-49 |
ISSN: | 0022-1139 |
DOI: | 10.1016/0022-1139(95)03294-n |
Popis: | Perfluoro-2,3-dihydrobenzo[b] thiophene (I), along with some quantities of perfluoroindane, has been obtained by copyrolysis of a number of 4-substituted tetrafluorothiophenols with tetrafluoroethylene in the presence of iodine. The interaction of sulphide I with some nucleophilic and oxidizing agents has been studied. The 5-and 6-substituted derivatives of polyfluoro-2,3-dihydrobenzothiophene have been synthesized. |
Databáze: | OpenAIRE |
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