Tetracoordinate phosphorus cage compounds with endocyclic P–C bonds: Synthesis and reactivity
| Autor: | G. A. Ivkova, Liliya M. Burnaeva, Vladimir F. Mironov |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Tetracoordinate
010405 organic chemistry Phosphorus Intramolecular cyclization chemistry.chemical_element General Chemistry Electrophilic aromatic substitution 010402 general chemistry 01 natural sciences Medicinal chemistry Cycloaddition 0104 chemical sciences chemistry.chemical_compound chemistry Organic chemistry Reactivity (chemistry) Cage Phosphine |
| Zdroj: | Russian Journal of General Chemistry. 86:2624-2635 |
| ISSN: | 1608-3350 1070-3632 |
| Popis: | The survey summarizes modern methods of synthesis and reactivity of tetracoordinated phosphorus cage compounds containing one or more endocyclic P–C bonds (phosphine oxides, phosphinates and phosphonates, phosphatripticenes and others). Intramolecular cyclization reactions including electrophilic aromatic substitution with unsaturated organophosphorus compounds, reactions of P–H-derivatives with carbonyl compounds as well as cycloaddition reactions involving I–IV-coordinated phosphorus derivatives are considered. |
| Databáze: | OpenAIRE |
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