Tchebichef-Hermite image moment method: A novel tool for chemometric analysis of three-dimensional spectra
| Autor: | Bao Qiong Li, Shao Hua Lu, Hong Lin Zhai, Xue Wang, Min Li Xu |
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| Rok vydání: | 2017 |
| Předmět: |
Image moment
Hermite polynomials Basis (linear algebra) 010405 organic chemistry Process Chemistry and Technology 010401 analytical chemistry computer.software_genre Multiple target 01 natural sciences Spectral line 0104 chemical sciences Computer Science Applications Analytical Chemistry Moment (mathematics) Information extraction Statistics computer Algorithm Spectroscopy Software Mathematics |
| Zdroj: | Chemometrics and Intelligent Laboratory Systems. 167:36-43 |
| ISSN: | 0169-7439 |
| Popis: | Image moment methods have been applied to the qualitative and quantitative analyses in analytical chemistry owing to their availability. As another attractive image moment method, Tchebichef-Hermite moment (THM) method was proposed for the first time in this work, which originated from the Tchebichef moment method and Hermite moment method. The performances of the THM method were tested with two instances for the quantitative analysis of multiple target compounds on the basis of HPLC-PAD and LC-MS three-dimensional (3D) spectra, respectively. Experimental results indicate that the THM method not only inherits the common advantages of these discrete orthogonal moments to deal with some fundamental challenges (such as partially overlapped signals, uncalibrated interferences, peak shifts and baseline drifts) during the analytical process of different kinds of 3D spectra, but also has its unique superiority in information extraction ability that simplify the determination of optimum maximal orders in moment methods. Compared with the previously used Tchebichef moment method, THM method is much more convenient and efficient. |
| Databáze: | OpenAIRE |
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