Penicillin-cephalosporin conversion. VIII. Synthesis of 2,3'-bisthio-substituted cephalosporins via electrolytic chlorination of thiazolinoazetidinone

Autor:	Hideo Tanaka, Michio Sasaoka, Sigeru Torii, Takashi Siroi
Rok vydání:	1983
Předmět:	Intramolecular reaction Bicyclic molecule medicine.drug_class Organic Chemistry Cephalosporin Electrolyte Electrochemistry Medicinal chemistry Penicillin chemistry.chemical_compound chemistry medicine Lactam Bond cleavage medicine.drug
Zdroj:	The Journal of Organic Chemistry. 48:3551-3553
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo00168a036
Popis:	A partir de benzyl-3 «α»-isopropenyl oxo-7 thia-4 diaza-2,6 bicyclo [3.2.0] heptene-2 carboxylate-6 de benzyle, par l'intermediaire de chloration electrochimique, de scission, puis de recyclisation, obtention de R-2 R-methyl-3 phenylacetamido-7 cepheme-3carboxylates-4 de benzyle (R=benzothiazolyl-2thio, methyl-5 thiadiazole-1,3,4yl-2thio ou benzenesulfonyl)
Databáze:	OpenAIRE
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