Interaction of electron acceptors with bases—III

Autor:	R. Foster, Raymond K. Mackie
Rok vydání:	1962
Předmět:	chemistry.chemical_classification Absorption spectroscopy Chemistry Organic Chemistry Electron acceptor Photochemistry Biochemistry Ion chemistry.chemical_compound Ionization Amide Drug Discovery Nucleophilic substitution Nitro Absorption (chemistry)
Zdroj:	Tetrahedron. 18:161-168
ISSN:	0040-4020
DOI:	10.1016/0040-4020(62)80035-0
Popis:	The visible region absorption spectra of a series of substituted polynitrobenzenes in liquid ammonia has been measured. It is suggested that the absorption is produced by the respective pentadienyl anion formed by the attachment of the amide ion to the ring carbon atom of the polynitrobenzene which is ortho or para to the maximum number of nitro groups. Such structures have been proposed by Bunnett as intermediates in aromatic nucleophilic substitution reactions. Of the compounds studied primary and secondary aromatic nitro-anilines are exceptional, in that ionization appears to occur by loss of a proton from the amino group.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7b918d02428c238f1d9cef0d7bc62292 https://doi.org/10.1016/0040-4020(62)80035-0 Zobrazit plný text záznamu