Development Of The Universal Extraction (Unex) Process For The Simultaneous Recovery Of Cs, Sr, And Actinides From Acidic Radioactive Wastes

Autor: Vasily Babain, Igor V. Smirnov, Jack D. Law, R. Scott Herbst, V. N. Romanovskiy, Terry A. Todd, V. N. Esimantovskiy, B. N. Zaitsev
Rok vydání: 2003
Předmět:
Zdroj: Separation Science and Technology. 38:2685-2708
ISSN: 1520-5754
0149-6395
Popis: A synergistic extraction mixture containing chlorinated cobalt dicarbollide (CCD), polyethylene glycol (PEG), and diphenyl-N,N-dibutylcarbamoyl phosphine oxide (CMPO) in a suitable polar diluent is being developed for the simultaneous recovery of Cs, Sr, and the actinides from highly acidic radioactive wastes. Development of this UNEX process was by a successful collaboration between scientists from the Idaho National Engineering and Environmental Laboratory (INEEL) and the Khlopin Radium Institute (KRI) in St. Petersburg, Russia. Development efforts focused on the treatment of radioactive waste currently stored at the INEEL. The development of the UNEX process has and continues to be an evolutionary process. Numerous countercurrent flowsheet demonstrations have been conducted to date, including two tests with several liters of actual radioactive tank waste, one test with dissolved radioactive calcine, and several tests with surrogate INEEL tank and dissolved calcine wastes. All countercurrent flowsheet t...
Databáze: OpenAIRE