Ligands of biologically active compounds in the nanochemistry of silver and gold (A review)

Autor:	V. P. Pchelkin, R. P. Evstigneeva
Rok vydání:	2006
Předmět:	Pharmacology chemistry.chemical_classification Degree of unsaturation Olefin fiber Coordination number Nanochemistry Combinatorial chemistry Silver nanoparticle Coordination complex Metal chemistry visual_art Drug Discovery visual_art.visual_art_medium Molecule Organic chemistry
Zdroj:	Pharmaceutical Chemistry Journal. 40:211-221
ISSN:	1573-9031 0091-150X
Popis:	Examples of the interactions of gold and silver clusters with various organic compounds containing olefinic and carbonyl groups capable of acting as ligands for the formation of coordination compounds with these metals are considered. Common physicochemical properties of the coordination complexes of silver ions with olefins are described. The behavior of olefins as ligands of the coordination complexes with silver ions in liquid chromatographic systems is analyzed. There is a correlation between the lipophilicity of such organic molecules and the possible variations of the coordination numbers of metal atoms, as well as between the degree of unsaturation of olefin chains in these molecules and the electrical conductivity of thin films of related lipids (including those of natural origin). Such complexes can be used in nanotechnology for the creation of biocomputer memory cells.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7b7d997cbcacc591b2fb6c785fba8aeb https://doi.org/10.1007/s11094-006-0094-7 Zobrazit plný text záznamu Plný text ve formátu PDF