Hochsubstituierte decabenzylmetallocene: Synthese und strukturaufklärung von deca(4-acetylbenzyl)ferrocen Fe[C5(CH2C6H4C(O)CH3)5]2

Autor:	Herbert Schumann, Roman Weimann, Klaudia Sühring
Rok vydání:	1995
Předmět:	Inorganic Chemistry chemistry.chemical_compound Ferrocene chemistry Acetyl chloride Stereochemistry Organic Chemistry Materials Chemistry Physical and Theoretical Chemistry Biochemistry Friedel–Crafts reaction Medicinal chemistry Deca
Zdroj:	Journal of Organometallic Chemistry. 496:C5-C8
ISSN:	0022-328X
Popis:	Decabenzylferrocene reacts with acetyl chloride in the presence of Al2Cl6 to form Deca(4-acetylbenzyl)ferrocene Fe[C5-(CH2C6H4C(O)CH3)5]2 (2). The X-ray structure confirms the all-para-substitution of the ten benzylligands by the acetyl group. 2 crystallizes in the space group P 2 1 n with a = 1479.8(3) pm, b = 1700.9(4) pm, c = 1618.7(8) pm, β = 89.99(2)° and V = 4074(2) × 10−30 m3. The final refinement resulted in R = 0.0936 for 3983 observed reflections with Fo ≥ 2σ(Fo).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7b654bcaf18f8df2868a8654ba6c1b7c https://doi.org/10.1016/0022-328x(95)05551-y Zobrazit plný text záznamu Full Text from ScienceDirect