Pressure-Induced Valence Transition and Heavy Fermion State in Eu2Ni3Ge5 and EuRhSi3

Autor: Katsuya Shimizu, Yoshichika Ōnuki, Takao Nakama, Shuei Kayama, Tomoko Kagayama, Taro Uejo, Ai Nakamura, Miho Nakashima, Yoshiya Uwatoko, Tomoya Okazaki, Yasushi Amako, Hiromu Akamine, Masato Hedo, Hiroyuki Shiba, Kazuyuki Matsubayashi
Rok vydání: 2015
Předmět:
Zdroj: Journal of the Physical Society of Japan. 84:053701
ISSN: 1347-4073
0031-9015
DOI: 10.7566/jpsj.84.053701
Popis: We succeeded in growing single crystals of Eu2Ni3Ge5 and EuRhSi3 by the In-flux method, and measured the electrical resistivity under pressures. Both compounds are Eu-divalent antiferromagnets with the Neel temperatures TN = 18.6 and 47.7 K, respectively. With increasing pressure, the resistivity in Eu2Ni3Ge5 indicates a clear kink at Tv = 220 K under 8.0 GPa, for example, which corresponds to a valence transition. The valence of Eu ions deviates from divalence toward trivalence. Correspondingly, antiferromagnetic ordering disappears completely. The low-temperature resistivity is, surprisingly, very similar to the resistivity of a well-known heavy fermion superconductor CeCu2Si2, possessing a two-peak-structure based on the Kondo effect. In fact, the A value of the resistivity ρ = ρ0 + AT2 in the Fermi liquid relation becomes large, A = 0.3 µΩ·cm/K2 at 8.0 GPa. The similar characteristic features are observed in another compound EuRhSi3.
Databáze: OpenAIRE