Proton-acceptor properties of azahomofullerene and fullerenoaziridine containing a cyanuric acid fragment

Autor:	A. R. Mustafina, Sh. K. Latypov, Irina P. Romanova, O. A. Larionova, Oleg G. Sinyashin, A. A. Balandina, Vladislav V. Zverev, V. V. Skripacheva
Rok vydání:	2008
Předmět:	Lone electron pair chemistry.chemical_compound Fullerene chemistry Stereochemistry Fragment (computer graphics) Proton NMR Proton affinity General Chemistry Cyanuric acid Medicinal chemistry Proton acceptor
Zdroj:	Russian Journal of General Chemistry. 78:451-456
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363208030201
Popis:	13C and 1H NMR and UV spectral studies on 1,3-diallyl-5-[4-(azahomo[60]fullereno)butyl]hexahydro-1,3,5-triazine-2,4,6-trione ([5,6]-open isomer) and 1,3-diallyl-5-[4-(aziridino[60]fullereno)butyl]hexahydro-1,3,5-triazine-2,4,6-trione ([6,6]-closed isomer), as well as quantum-chemical calculations, showed that only the latter possesses weakly basic properties.
Databáze:	OpenAIRE
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