Magneto-structural correlations in self-assembled spin-transition nano-architectures of the [][2×2]-grid-type

Autor:	Jean-Marie Lehn, G Vaughan, Esther Breuning, Mario Ruben, P. Gütlich, Vadim Ksenofontov
Rok vydání:	2004
Předmět:	Materials science Magnetism Ligand Spin transition Supramolecular chemistry Substituent Condensed Matter Physics Magnetic susceptibility Electronic Optical and Magnetic Materials Ion Crystallography chemistry.chemical_compound chemistry Diamagnetism
Zdroj:	Journal of Magnetism and Magnetic Materials. :E715-E717
ISSN:	0304-8853
DOI:	10.1016/j.jmmm.2003.12.1423
Popis:	The magnetism of a series of tetranuclear complexes of the [ Fe II 4 L 4 ]( BF 4 ) 8 [2×2] -grid-type was investigated, revealing the occurrence of spin-transition (ST) behavior within this class of compounds. The phenomenon depends directly on the nature of the substituent R1 of the ligand L . All FeII ions in compounds with R1 substituents favoring strong ligand fields ( R 1 = H ; OH ) remain completely in the diamagnetic low-spin state. Only the complex bearing R1=Ph exhibits thermally induced ST behavior.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7b31d4bb495b1ffa6253594a570bd883 https://doi.org/10.1016/j.jmmm.2003.12.1423 Zobrazit plný text záznamu Full Text from ScienceDirect