Hydrogenation of Alkenes Catalyzed by Dinuclear Thiolato Bridged Rhodium(I) Complexes

Autor:	Philippe Kalck, Alain Rovera, Antoine Gaset, Rene-Paul Martin, René Poilblanc
Rok vydání:	1980
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Organic Chemistry Materials Chemistry Cyclohexene Organic chemistry chemistry.chemical_element Physical and Theoretical Chemistry Biochemistry Medicinal chemistry Catalysis Rhodium
Zdroj:	Journal of Organometallic Chemistry. 195:C13-C14
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)93395-3
Popis:	The catalytic activities of the complexes [Rh2(μ-SR)2(CO)2L2] for the hydrogenation of 1-hexene or cyclohexene have been examined at low pressure; the best yields were observed for L  phosphite. The tetrasubstituted complexes [Rh2(μ-SR)2(P(OR′)3)4] were found to be very active catalysts for the same reaction; turnover rates as high as 15 min—1 were observed at 20°C and 1 atm of H2.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7b30ebf973ad6a24faccc76d831133c2 https://doi.org/10.1016/s0022-328x(00)93395-3 Zobrazit plný text záznamu