ChemInform Abstract: The Covalent Casting of One-Dimensional Hydrogen Bonding Motifs: Toward Oligomers and Polymers of Predefined Topography

Autor:	Eric A. Archer, Adrienne E. Sochia, Michael J. Krische
Rok vydání:	2010
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Crystallography chemistry Hydrogen bond Duplex (building) Casting (metalworking) Covalent bond General Medicine Polymer DNA
Zdroj:	ChemInform. 33
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200204278
Popis:	The covalent casting of noncovalent architectures serves to define large covalent constructs that express well-defined modes of aggregation. In the case of one-dimensional hydrogen-bonding motifs, covalent casting yields molecular strands that adopt a duplex mode of aggregation. The effectiveness of this design principle is illustrated through the casting of the aminotriazine hydrogen-bonding motif. These studies have led to the conception of a new family of topographically defined oligomers, which, akin to DNA, self-assemble in the form of a duplex through the action of interstrand hydrogen bonds.
Databáze:	OpenAIRE
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