Importance of small loops within PIM-1 topology on gas separation selectivity in thin film composite membranes
| Autor: | Joseph L. Beal, Jose Miguel Luque-Alled, Peter M. Budd, Andrew B. Foster, Michael Mathias, Ben Robertson, Marzieh Tamaddondar, Patricia Gorgojo |
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| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Materials science Renewable Energy Sustainability and the Environment Polyacrylonitrile General Chemistry Permeance Polymer Branching (polymer chemistry) Topology chemistry.chemical_compound Membrane chemistry Polymerization Thin-film composite membrane General Materials Science Gas separation |
| Zdroj: | Journal of Materials Chemistry A. 9:21807-21823 |
| ISSN: | 2050-7496 2050-7488 |
| Popis: | Studies of blends of topologically distinct samples of the polymer of intrinsic microporosity PIM-1 demonstrate, for the CO2/N2 gas pair, the ability to vary dramatically the selectivity and aging behaviour of thin film composite (TFC) membranes. Polymerizations carried out in the absence of nitrogen gas produced polymers with higher degrees of branching, which formed further into loops and at higher temperatures into significant amounts of colloidal network PIM-1 ( |
| Databáze: | OpenAIRE |
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