| Popis: |
Diphenylphosphorylazide N 3 P(O)(OPh) 2 reacts with Pt(PPh 3 ) 3 , Pt(PPh 3 ) 2 (C 2 H 4 ), trans -RhCl(CO)(PPh 3 ) 2 , Ru(CO) 3 (PPh 3 ) 2 , CoCl 2 (PPh 3 ) 2 and CuCl(PPh 3 ) 2 to give the azido complexes Pt(PPh 3 ) 2 (N 3 )R, Pt(PPh 3 ) 2 (N 3 ) 2 R 2 , the urylene complex RhCl(PPh 3 ) 2 (RNCONR) and the phosphine imine complexes Ru(CO) 3 (RPPh 3 ) 2 , CoCl 2 (RNPPh 3 ) 2 , CuCl(RNPPh 3 ) 2 , respectively, (RP(O)(OPh) 2 ). The oxidative addition of n-C 6 F 13 SO 2 N 3 to Pt(PPh 3 ) 4 and Pt(PPh 3 ) 2 (C 2 H 4 ) affords the complexes Pt(PPh 3 ) 2 (N 3 )R and Pt(PPh 3 ) 2 (N 3 ) 2 R 2 , respectively, (RSO 2 C 6 F 13 . The compounds are characterized by elemental analysis and by their IR spectra. |
